N-(2,6-Dimethylphenyl)benzenesulfonamide
نویسندگان
چکیده
In the crystal structure of the title compound, C(14)H(15)NO(2)S, the N-H bond is trans to one of the S=O double bonds, similar to what is observed in N-(2-methyl-phen-yl)benzene-sulfonamide and other aryl sulfonamides. The two aromatic rings enclose a dihedral angle of 44.9 (1)°. The mol-ecules are connected by inter-molecular N-H⋯O hydrogen bonds into chains running along the a axis. An intermolecular C-H⋯O hydrogen bond is also present.
منابع مشابه
2,4-Dichloro-N-(2,6-dimethylphenyl)benzenesulfonamide
In the crystal of the title compound, C(14)H(13)Cl(2)NO(2)S, the N-H bond in the C-SO(2)-NH-C segment orients itself away from the two ortho-methyl groups in the aniline benzene ring and towards the ortho-chloro group of the sulfonyl benzene ring. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -100.48 (18)°. The sulfonyl and aniline benzene rings are tilted relative to...
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In the title compound, C(14)H(14)ClNO(2)S, the amido H atom orients itself away from both the ortho-methyl groups in the adjacent aromatic ring. The mol-ecule is twisted at the S atom with an C-SO(2)-NH-C torsion angle of -69.9 (2)°. The two aromatic rings are tilted relative to each other by 31.9 (1)°. In the crystal, the mol-ecules are packed into zigzag chains along the b axis via inter-mole...
متن کامل4-Chloro-N-(2,3-dimethylphenyl)benzenesulfonamide
In the title compound, C(14)H(14)ClNO(2)S, the two aromatic rings are tilted relative to each other by 34.7 (1)°. In the crystal, the mol-ecules form zigzag chains along the c axis via inter-molecular N-H⋯O hydrogen bonds.
متن کاملN-(2,5-Dimethylphenyl)benzenesulfonamide
In the title compound, C(14)H(15)NO(2)S, the dihedral angle between the aromatic rings is 40.4 (1)° relative to each other. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.
متن کامل4-Chloro-N-(3,4-dimethylphenyl)benzenesulfonamide
In the title compound, C(14)H(14)ClNO(2)S, the angle between the sulfonyl and aniline benzene rings is 65.5 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O hydrogen bonds. The dimethyl-phenyl ring is disordered over two different orientations approximately related by a 180° rotation about the C-N bond, with occupancies of 0.643 (6) and 0.357 (6).
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